期刊
APPLIED SURFACE SCIENCE
卷 314, 期 -, 页码 476-480出版社
ELSEVIER
DOI: 10.1016/j.apsusc.2014.07.035
关键词
Pulsed laser deposition; Zinnwaldite Mica; Vanadium dioxide; Thermochromism; Electrical properties; Phase transition
类别
资金
- National Research Foundation of South Africa (NRF) [89293]
- French Centre National pour la Recherche Scientifique, iThemba LABS
- UNESCO-UNISA Africa Chair in Nanosciences Nanotechnology
- Organization of Women in Science for the Developing World (OWSDW)
- Abdus Salam ICTP via the Nanosciences African Network (NANOAFNET)
- African Laser Centre (ALC)
VO2 thin films have been deposited by pulsed laser deposition on Zinnwaldite Mica substrates. The crystal structure, chemical composition, morphology were determined and the semiconductor/metal transition (SMT) properties of the deposited films were investigated. Without any post annealing, the films exhibit a textured nature with a VO2 (0 1 1) preferred crystallographic orientation and an elevated thermal variation of the electric resistance ratio R-S/R-M through the SMT at T approximate to 68 degrees C of the order of 10(4) and a narrow similar to 7 degrees C hysteresis. In addition, the growth of the VO2 crystallites seem to be governed likely by a Volmer-Weber or Stranski-Krastanov mechanisms and certainly not a Frank-van Der Merwe process. (C) 2014 Elsevier B.V. All rights reserved.
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