期刊
APPLIED SURFACE SCIENCE
卷 280, 期 -, 页码 914-919出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.apsusc.2013.05.094
关键词
Graphene; Functional; Composite materials; Phthalocyanine
类别
资金
- National Science Foundation of China [J0830415]
An efficient and convenient method is applied to introduce varieties of simple functionalities onto the graphene surface for the bulk preparation, which begins with pristine graphite that does not require initial oxidative damage of the graphene basal planes. Diazonium compounds functionalized reaction is demonstrated and it successfully prevented the aggregation of graphene for which providing solubility in high polar organic media or even in volatile solvents such as ethanol and acetone. This approach is complemented by the phenyl carboxylic diazonium salt functionalized graphene (PCFG) attachment of a symmetrically substituted zinc phthalocyanine (PCFG-Pc) using the amide reaction, which is used for the covalent introduction of a complex phthalocyanine molecule. (C) 2013 Elsevier B.V. All rights reserved.
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