期刊
APPLIED SURFACE SCIENCE
卷 284, 期 -, 页码 745-749出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.apsusc.2013.08.004
关键词
Molecularly imprinted polymers; Quantum dots; Magnetic nanoparticles; Endocrine disrupting chemicals
类别
资金
- National Natural Science Foundation of China [21176052]
- State Key Lab of Urban Water Resource and Environment (HIT) [2013TS05]
In this study, we present a general protocol to fabricate imprinting matrix co-loaded with CdTe quantum dots and Fe3O4 nanoparticles for the recognition of endocrine disrupting chemicals (EDCs). The resultant composites were characterized by transmission electron microscopy, fluorescence spectroscopy, and energy dispersive spectroscopy. The materials have been demonstrated to be characterized with spherical shape with a saturation magnetization value of 1.7 emu g(-1). Furthermore, the rebinding experiments show that the resultant materials have greater affinity and selectivity towards p-nitrophenol (model EDCs) over structurally related compounds. We believe that the effective method proposed in this work might provide a platform to prepare magnetic and fluorescent molecularly imprinted polymers for the recognition and separation of EDCs. (C) 2013 Elsevier B. V. All rights reserved.
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