期刊
APPLIED SURFACE SCIENCE
卷 265, 期 -, 页码 802-809出版社
ELSEVIER
DOI: 10.1016/j.apsusc.2012.11.122
关键词
Gold nanostructure; Potential sweep transient; Potential step transient; Adsorptive ion
类别
资金
- Chongqing Key Scientific and Technological Program Project of China [cstc2011ggB0015]
- National Natural Science Foundation of China [61275061]
- West Light Foundation of The Chinese Academy of Sciences
The ultrathin gold film and gold nanoprism immobilized on ITO electrodes displayed strong perturbed plasmonic scattering as the result of potential linear sweep and step applications. Although nanoscale surface structure strongly determines the potential-dependent plasmonic response of gold nanostructure, the universality of exponential fit for the differential scattering induced by the potential linear sweep indicates the same mechanism could be widely used to explain the effect of potential on the gold nanostructure. The larger scattering changed by the anodic potential step than cathodic counterpart is attributed to increased double layer capacitance due to the presence of adsorptive ion. The presence of potential controlled scattering indicates the tunability of localized surface plasmon resonance of gold nanostructure. (c) 2012 Elsevier B.V. All rights reserved.
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