Imaging of Ti0.87O2 nanosheets using scanning tunneling spectroscopy

We report scanning tunneling microscopy (STM) and spectroscopy (STS) measurements on single layer Ti0.87O2 nanosheets deposited on Pt(200 nm)/Si substrates. These nanosheets have a band gap of 3.8 eV and are virtually invisible in conventional STM images. However, an impressive contrast is observed in the di/dz map, which allows for a clear identification of the nanosheets. The di/dz signal is obtained by adding a high frequency, small amplitude modulation to the z-piezo using a lock-in amplifier. (C) 2012 Elsevier B.V. All rights reserved.