期刊
INORGANICA CHIMICA ACTA
卷 357, 期 9, 页码 2525-2531出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ica.2004.03.012
关键词
octamolybdate; isomer; organic inorganic hybrid; crystal structure
A new octamolybdate-supported transition metal complex [{Ni(phen)(2)}(2)(Mo8O26)] (1) has been hydrothermally synthesized and characterized by the elemental analyses, IR spectrum, XPS spectra, TG analysis and the single crystal X-ray diffraction. Compound I crystallizes in the monoclinic space group P2(1)/c, a = 10.446(2) Angstrom, b = 12.103(2) Angstrom, c = 21.956(4) Angstrom, beta = 97.81(3)degrees, V = 2750.0(10) Angstrom(3), and Z = 2. The single crystal X-ray diffraction analysis reveals that compound I is constructed from a novel unprecedented eta-type octamolybdate cluster linked to two {Ni(phen)(2)}(2) coordination complexes. (C) 2004 Elsevier B.V. All rights reserved.
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