Preparation of activated carbon from Enteromorpha prolifera and its use on cationic red X-GRL removal

Enteromorpha prolifera was pyrolyzed to prepare activated carbon using chemical activation by zinc chloride. The effect of activation parameters such as activation temperature, weight ratio ( Enteromorpha prolifera to ZnCl2), and activation time was investigated. The BET results showed that the surface area and pore volume of activated carbons were achieved as high as 1722 m(2)/g and 1.11 cm(3)/g, respectively, in the optimal activation conditions. Batch adsorption studies were carried out to study the adsorption properties of cationic red X-GRL onto activated carbon by varying the parameters like initial solution pH, contact time, and temperature. The kinetic studies showed that the adsorption data followed a pseudo second-order model. The isotherm analysis indicated that the adsorption data could be represented by the Langmuir isotherm model. The Langmuir monolayer adsorption capacity of cationic red X-GRL was estimated as 263.16 mg/g at pH 6.0. (C) 2011 Elsevier B.V. All rights reserved.