期刊
MACROMOLECULAR RAPID COMMUNICATIONS
卷 25, 期 14, 页码 1309-1313出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/marc.200400148
关键词
freezing-point depression; nanocomposites; organoclay; rubber
A novel experimental approach based on the freezing-point depression of a solvent in a swollen gel has been developed to characterize the structure of nanocomposites. A higher depression in the freezing point has been related with an exfoliated nanocomposite. This increased depression not only depends on the formation of a tighter network but also on the decrease of the size of the solvent cages where the nucleation takes place.
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