期刊
TETRAHEDRON
卷 60, 期 31, 页码 6437-6442出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2004.06.051
关键词
piperidine alkaloids; quinolizidine; ring rearrangement metathesis; Grubbs' catalyst
A ruthenium-catalyzed ring opening-ring closing metathesis reaction serves as the key step in the stereoselective synthesis of a new enantiopure 2-substituted-4.5-dehydropiperidine skeleton, a valuable intermediate for the synthesis of piperidine alkaloids (such as halosaline) and of hydroxylated quinolizidines (such as (2R,9aR)-(+)-2-hydroxy-quinolizidine). (C) 2004 Elsevier Ltd. All rights reserved.
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