Synthesis, characterization and effect of calcination temperature on phase transformation and photocatalytic activity of Cu,S-codoped TiO2 nanoparticles

A novel copper and sulfur codoped TiO2 photocatalyst was synthesized by modified sol-gel method using titanium(IV) isopropoxide, CuCl2 center dot 2H(2)O and thiourea as precursors. The samples were characterized by X-ray diffraction (XRD), diffuse reflectance spectroscopy (DRS), scanning electron microscopy equipped with energy dispersive X-ray micro-analysis (SEM-EDX), transmission electron microscopy (TEM) and Fourier transform infrared (FT-IR) analysis. The XRD results showed undoped and Cu,S-codoped TiO2 nanoparticles only include anatase phase. Effect of calcination temperature showed rutile phase appears in 650 and 700 degrees C for undoped and 0.1% Cu, S-codoped TiO2, respectively. The SEM analysis revealed the doping of Cu and S does not leave any change in morphology of the catalyst surface. The increase of copper doping enhanced red-shift'' in the UV-vis absorption spectra. The TEM images confirmed the dopants suppressed the growth of TiO2 grains. The photocatalytic activity of samples was tested for degradation of methyl orange (MO) solutions. The results showed photocatalytic activity of the catalysts with 0.05% Cu, 0.05% S and 0.1% Cu, 0.05% S were higher than that of other catalysts under ultraviolet (UV) and visible irradiation, respectively. Because of synergetic effect of S and Cu, the Cu, S-codoped TiO2 catalyst has higher activity than undoped and Cu or S doped TiO2 catalysts. (C) 2009 Elsevier B. V. All rights reserved.