期刊
ACCOUNTS OF CHEMICAL RESEARCH
卷 37, 期 8, 页码 558-569出版社
AMER CHEMICAL SOC
DOI: 10.1021/ar0300524
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Computational studies have led to models to understand some classic and contemporary asymmetric reactions involving organo-catalysts. The Hajos-Parrish-Eder-Sauer-Wiechert reaction and intermolecular aldol reactions as well as Mannich reactions and oxyaminations catalyzed by proline and other amino acids, and Diels-Alder reactions catalyzed by MacMillan's chiral amine organocatalysts have been studied with density functional theory. Quantitative predictions for several new catalysts and reactions are provided.
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