期刊
JOURNAL OF MAGNETIC RESONANCE
卷 169, 期 2, 页码 313-322出版社
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jmr.2004.05.002
关键词
low-field NMR; He-3; hyperpolarized gas; restricted diffusion; apparent diffusion coefficient; Gaussian phase approximation; cylindrical pore
The time-dependent diffusion of He-3 atoms perpendicular to the axis of a single macroscopically large cylindrical pore is studied using a steady (or constant) gradient-recalled echo sequence. Measurements of the effective He-3 diffusion coefficient extending from the free-diffusion regime to the motionally averaged regime are presented, and are well-described by analytic solutions to the Bloch-Torrey equation based on the gaussian phase approximation. Our data yield the value 0.140(6) m(2)/s for the self diffusion coefficient of He-3 at a temperature of 296 K and a pressure of 1.00 Torr. Adaptations of these methods should enable the study of complex pore geometries as model systems. (C) 2004 Elsevier Inc. All rights reserved.
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