期刊
SOLID STATE NUCLEAR MAGNETIC RESONANCE
卷 26, 期 1, 页码 1-10出版社
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/S0926-2040(03)00062-6
关键词
solid-state NMR; deuteron NMR; magic-angle spinning; molecular dynamics
The H-2 NMR magic-angle spinning (MAS) technique is compared to the static-powder quadrupole echo (QE) and Jeener-Brockaert (JB) pulse sequences for a quantitative investigation of molecular dynamics in solids. The linewidth of individual spinning sidebands of the one-dimensional MAS spectra are observed to be characteristic of the correlation time from similar to10-2 to similar to 10(-8) s so that the dynamic range is increased by approximately three orders of magnitude when compared to the QE experiment. As a consequence, MAS H-2 NMR is found to be more sensitive to the presence of an inhomogeneous distribution of correlation times than the QE and JB experiments which rely upon lineshape distortions due to anisotropic T-2 and T-1Q relaxation, respectively. All these results are demonstrated experimentally and numerically using the two-site flip motion of dimethyl sulfone and of the nitrobenzene guest in the alpha-p-tert-butylcalix[4]arene-nitrobenzene inclusion compound. (C) 2003 Elsevier Inc. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据