The production technology of Iznik pottery - A reassessment

Previous research has established that Iznik pottery differs from other Islamic stonepaste pottery in that its stonepaste bodies contain lead oxide as well as soda and lime, and that a significant proportion of the tin oxide in its glaze is present in solution rather than as tin oxide particles. In order to better understand these distinguishing features, the chemical compositions and microstructures of Iznik pottery and tile samples, together with those of lumps of glass found in association, were investigated using both scanning electron and optical microscopy. These data have been supplemented by the study of replicate lead-alkali glazes produced in the laboratory with a range of different compositions. The results demonstrate that separate soda-lime and high-lead glasses were used in the production of Iznik stonepaste bodies, and that the total glass contents of the bodies were significantly higher than those quoted by Abu'l-Qasim, who was writing in about AD 1300. The very high purity of the lead-soda Iznik glazes indicated that the alkali flux used was either a purified plant ash or an as vet unidentified mineral source of soda. Replication experiments established that the high solubility of tin oxide it? the glaze was due to the high purity of the glaze constituents. Furthermore, it is suggested that tin oxide was added to the glaze in order to give it a very slight opacity and thus obscure any blemishes in the underlying body.