期刊
APPLIED SPECTROSCOPY
卷 64, 期 12, 页码 1374-1378出版社
SAGE PUBLICATIONS INC
DOI: 10.1366/000370210793561646
关键词
Polarization-modulation infrared reflection absorption spectrometry; PM IRRAS; Langmuir monolayer film; Quality of spectra; Surface selection rules; Optimal angle of incidence
资金
- Ministry of Education Science Sports Culture and Technology Japan [20350035, 21020012]
- Grants-in-Aid for Scientific Research [20350035, 21020012] Funding Source: KAKEN
Quality analysis of polarization modulation infrared reflection absorption spectrometry (PM-IRRAS) for measurements of a Langmuir (L) monolayer film on water is presented The spectral quality represented by the signal to-noise ratio is evaluated by taking into account both the band intensity and the electrical signal throughput led out from the Fourier transform Infrared (FT-IR) spectrometer The product of the two parameters, which is named the quality evaluation function, theoretically reveals the optimal angle of incidence for the L film measurements In addition, the PM IRRAS-specific surface selection rule with respect to the spectral quality is also presented
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