Advanced method using microwaves and solid-phase microextraction coupled with gas chromatography-mass spectrometry for the determination of pyrethroid residues in strawberries

A microwave-assisted desorption method was developed and coupled with solid-phase microextraction and GC-MS for the analysis of pyrethroid residues in strawberries. In the first step, pyrethroid analytes were desorbed from the whole fruits in an aqueous acetonitrile solution at 50% under microwave assistance, so preventing these compounds to be captured with strong matrix effects by endogenous constituents. Then, the 100 mum poly(dimethylsiloxane)-coated fibre was exposed for 30 min in the obtained extracting solution. Calibration curves, realised from blank strawberries spiked at different concentrations with standards, showed a linear range between 1 mug/kg and 250 mug/kg with r(2) > 0.992 and variation coefficients below 15%. Limits of detection and quantitation were found lower than 14 mug/kg and 40 mug/kg, respectively. Observed analysis results by using this method and relative to field incurred strawberry samples were also compared to those obtained by two accredited trading laboratories using traditional methods. (C) 2004 Elsevier B.V. All rights reserved.