期刊
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
卷 570, 期 1, 页码 113-122出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jelechem.2004.03.023
关键词
poly(3,4-ethylenedioxythiophene); spectroelectrochemistry; ionic liquids; in situ ATR-FTIR; U-V-Vis spectroscopy
The electrochemical synthesis and the charging-discharging reactions of poly(3,4-ethylenedioxythiophene) (PEDOT) in two room-temperature ionic liquids, 1-butyl-3-methyl-imidazolium tetrafluoroborate (BMIMBF4) and 1-butyl-3-methyl-imidazolium hexafluorophosphate (BMIMPF6) were studied with cyclic voltammetry, in situ attenuated total reflection Fourier transform infrared (ATR-FTIR) spectroscopy and by in situ UV-Vis spectroelectrochemistry. The structures of the films prepared in ionic liquids was compared to PEDOT films prepared in common organic media. The doping induced changes in absorption of the material both in the mid infrared and in the UV-Vis region were studied and interpreted according to spectra reported for PEDOT films prepared from common organic media. (C) 2004 Elsevier B.V. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据