期刊
JOURNAL OF CHROMATOGRAPHY A
卷 1047, 期 1, 页码 101-109出版社
ELSEVIER
DOI: 10.1016/j.chroma.2004.06.113
关键词
soil; headspace analysis; mass spectrometry; gas chromatography; fast; chemometrics; environmental analysis; hydrocarbons
The direct coupling of a headspace sampler with a mass spectrometer is proposed as a screening tool for the rapid detection of soil pollution by hydrocarbons from petroleum and derivatives. The samples are subjected to the headspace generation process, with no prior treatment, and the volatiles generated are introduced directly into the mass spectrometer, thereby obtaining a fingerprint of the sample analysed. Suitable treatment of the signal by chemometric techniques allows unequivocal characterisation of the different types of sample. The use of fast gas chromatography with a mass spectrometer detector coupled to the headspace sampler allows identification of the major hydrocarbons present in the mineral and organic polluted samples, interpretation of the results obtained, and demonstrates the analytical potential of headspace-mass spectrometry coupling. (C) 2004 Elsevier B.V. All rights reserved.
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