期刊
APPLIED RADIATION AND ISOTOPES
卷 83, 期 -, 页码 47-55出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.apradiso.2013.10.013
关键词
Sequential extraction; U-series; Sediments; Clay separation
类别
资金
- iMQRES scholarship
- ARC [FT0990447, LP0990500, FT120100400]
- DEST Systematic Infrastructure Grants
- ARC LIEF
- NCRIS
- Macqaurie University
- Australian Research Council [FT0990447, LP0990500] Funding Source: Australian Research Council
The study of uranium-series (U-series) isotopes in soil and sediment materials has been proposed to quantify rates and timescales of soil production and sediment transport. Previous works have studied bulk soil or sediment material, which is a complex assemblage of primary and secondary minerals and organic compounds. However, the approach relies on the fractionation between U-series isotopes in primary minerals since they were liberated from the parent rock via weathering. In addition, secondary minerals and organic compounds have their own isotopic compositions such that the composition of the bulk material may not reflect that of primary minerals. Hence, there is a need for a sample preparation procedure that allows the isolation of primary minerals in soil or fluvial sediment samples. In this study, a sequential extraction procedure to separate primary minerals from soils and sediments was assessed. The procedure was applied to standard rock sample powders (TML-3 and BCR-2) to test whether it introduced any artefactual radioactive disequilibrium. A new step was introduced to remove the clay-sized fraction (< 2 mu m). Significant amounts (5-14%) of U and Th were removed from the rock standards during the procedure. No significant alteration in (U-234/U-238) and (Th-230/U-238) activity ratios of the rock standards occurred during the procedure. Aliquots of soil sample were subjected to the sequential extraction process to test how each step modifies the uranium-series activity ratios and mineralogy. Although no secondary minerals were detected in the unleached soil aliquots, the sequential leaching process removed up to 17% of U and Th and modified their activity ratios by up to 3%. The modification of the activity ratios poses a demand for careful means to avoid redistribution of isotopes back to the residual phase during phase extraction. (C) 2013 Elsevier Ltd. All rights reserved.
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