期刊
APPLIED RADIATION AND ISOTOPES
卷 69, 期 2, 页码 436-442出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.apradiso.2010.11.005
关键词
Tricarbonyltechnetium(I); Tricarbonylrhenium(I); Methyl thiosalicylate; Isocyanide; Stability; Lipophilicity
类别
资金
- Polish Ministry of Science and Higher Education [N N204 186039]
The complexes of [Tc-99m]-tricarbonyltechnetium(I) and [Re-188]-tricarbonylrhenium(I), of the '2 + 1' type, with methyl thiosalicylate as an anionic bidentate ligand and with either tert-butyl 3-isocyanopropionate or glycine-glycine-tyrosine 4-isocyanobutyrate as monodentate ligands, have been prepared on the n.c.a. scale. The complexes exhibit different lipophilicity and high stability in neutral aqueous solutions. Based on the results of the challenge experiment with histidine. cysteine and glutathione the studied complexes might be considered to be promising models for radiopharmaceutical precursors. (C) 2010 Elsevier Ltd. All rights reserved.
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