期刊
CATALYSIS TODAY
卷 93-5, 期 -, 页码 575-581出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.cattod.2004.06.107
关键词
VOC; Ag loaded zeolite HY; adsorption; catalytic oxidation; hydrophobic molecular sieve (HMS); dual functional adsorbent/catalyst
To design a good combined adsorbent/catalyst dual functional system for the control of the low concentration VOC, both adsorption and catalytic activity test over metal-loaded zeolite HY were carried out. Hydrophobic HY zeolite was selected as a good adsorbent candidate among the tested zeolite adsorbents and extended to the catalyst support material by adding various transition metals. The temperature programmed surface reaction (TPSR) of toluene and methylethylketone (MEK) suggested the silver as the best candidate among the tested transition metals. Temperature programmed reductions (TPR) and O-2-temperature programmed desorption (O-2-TPD) on Ag/HY catalysts were carried out to explain the nature of active centre of Ag catalyst for the toluene oxidation. Silver oxide species or partially oxidized metallic silver on to the surface of metallic silver phase was proposed as an active redox site during the oxidation reaction. (C) 2004 Elsevier B.V. All rights reserved.
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