期刊
ELECTROCHIMICA ACTA
卷 49, 期 21, 页码 3603-3611出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2004.03.030
关键词
ionic liquids; aliphatic quaternary ammonium salt; electric double layer capacitor; specific conductivity; specific capacitance
An aliphatic quaternary ammonium salt which has a methoxyethyl group on the nitrogen atom formed an ionic liquid (room temperature molten salt) when combined with the tetrafluoroborate (BF4-) and bis(trifluoromethylsulfonyl)imide [TFSI; (CF3SO2)(2)N-] anions. The limiting oxidation and reduction potentials, specific conductivity, and some other physicochemical properties of the novel ionic liquids, N,N-diethyl-N-methyl-N-(2-methoxyethyl)ammonium tetrafluoroborate (DEME-BF4) and DEME-TFSI have been evaluated and compared with those of 1-ethyl-3-methylimidazolium tetrafluoroborate. DEME-BF4 is a practically useful ionic liquid for electrochemical capacitors as it has a quite wide potential window (6.0 V) and high ionic conductivity (4.8 mS cm(-1) at 25 degreesC). We prepared an electric double layer capacitor (EDLC) composed of a pair of activated carbon electrodes and DEME-BF4 as the electrolyte. This EDLC (working voltage similar to2.5 V) has both, a higher capacity above room temperature and a better charge-discharge cycle durability at 100 degreesC when compared to a conventional EDLC using an organic liquid electrolyte such as a tetraethylammonium tetrafluoroborate in propylene carbonate. (C) 2004 Elsevier Ltd. All rights reserved.
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