期刊
RUSSIAN CHEMICAL BULLETIN
卷 53, 期 9, 页码 1993-1995出版社
SPRINGER
DOI: 10.1007/s11172-005-0060-7
关键词
metal-containing organosiloxanes; cobalt(II); UV spectroscopy; IR spectroscopy; kinetics of rearrangement
Intermolecular rearrangement of cobalt phenylsiloxanes was studied. The rearrangement leads to the formation Of Compounds with metal oxide moieties in the organosiloxane Structure and is accompanied by a change in the spectral characteristics of cobalt(II), determined by the second coordination sphere of the metal. The rate-determining step is the decomposition of an intermediate complex formed upon the coordination of the metal siloxane moieties.
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