期刊
SUPRAMOLECULAR CHEMISTRY
卷 16, 期 6, 页码 411-414出版社
TAYLOR & FRANCIS LTD
DOI: 10.1080/10610270412331286003
关键词
inclusion compounds; thiourea; semiconductor crystals; anisotropic properties
The anisotropic proton conductivity of a large-sized single crystal of the supramolecular, commensurate host-guest inclusion compound constituted by a polyanionic thiourea-chloride matrix defining channels in which the diquinuclidinium cations [Q(2)H](+) are hosted is reported. Specimens in the millimetre scale display an anisotropy factor of about 100, with electrical conductivities along molecular channels of the order of 10(-4) S cm(-1) at room temperature.
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