期刊
CHROMATOGRAPHIA
卷 60, 期 5-6, 页码 281-285出版社
SPRINGER HEIDELBERG
DOI: 10.1365/s10337-004-0342-5
关键词
column liquid chromatography; functionalized beta-cyclodextrin bonded stationary phases; chiral separation; organophosphorus enantiomers
The preparation, characterization and potential liquid chromatographic applications of two totally and partly functionalized beta-cycloclextrin-bonded stationary phases were presented. Separation of a series of organophosphorus racemic compounds was achieved under normal and reverse-phase conditions. Separation factor was up to 1.812 and resolution up to 4.072. The influence of chromatographic conditions was investigated and the possible chiral recognition mechanism was proposed.
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