期刊
POLYMER
卷 45, 期 19, 页码 6561-6567出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.polymer.2004.07.052
关键词
photopolymerization; photosensitive system; thiol-allyl ether and thiol-acrylate coatings
The photoinitiated polymerization reactions of thiol-allyl ether and thiol-acrylate mixtures under visible light in the presence of several visible photoinitiating systems have been investigated. Remarkable high yield of conversions as well as fast rates of polymerization are observed; a photoinitiating system based on Rose Bengal/Ferrocenium salt/hydroperoxide is particularly efficient. The role of a large variety of photoinitiating systems and the mechanisms involved in the initiation step are discussed. (C) 2004 Elsevier Ltd. All rights reserved.
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