期刊
SYNTHESIS-STUTTGART
卷 -, 期 13, 页码 2205-2209出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-2004-829179
关键词
aldehydes; corroles; macrocycles; oxidations; pyrroles
We have refined a one-pot synthesis of trans-A(2)B-corroles via the condensation of 5-(pentafluorophenyl)dipyrromethane with aldehydes followed by macrocyclization mediated by DDQ. After thorough examination of reaction parameters and thanks to the identification of key factors influencing the formation of bilanes and the efficiency of their conversion to corroles, we were able to improve yields from ca. 6 to ca. 20% for a broad range of aldehydes. We proved that these conditions work well also for dipyrromethanes possessing cyano and nitro groups. meso-Substituted alkyl aryl corrole has been obtained for the first time using this procedure.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据