期刊
JOURNAL OF HAZARDOUS MATERIALS
卷 113, 期 1-3, 页码 75-79出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jhazmat.2004.04.021
关键词
mercury(II); solid phase extraction; 1-(2-thiazolylazo)-2-naphthol functionalized activated carbon; hazardous chloralkali industrial wastes
As a part of removal of toxic heavy metals from hazardous wastes, solid phase extraction (SPE) of mercury(II) at trace and ultra trace levels was studied using 1-(2-thiazolylazo)-2-naphthol (TAN) functionalized activated carbon (AC). The SPE material removes traces of mercury(II) quantitatively in the pH range 6.0 +/- 0.2. Other parameters that influence quantitative recovery of mercury(II), viz. percent concentration of TAN in AC, amount of TAN-AC, preconcentration time and volume of aqueous phase were varied and optimized. The possible means of removal of Hg(II) from other metal ions that are likely to be present in the wastes of the chloroalkali industry is discussed. The potential of TAN-functionalized AC SPE material for decontaminating mercury from the brine sludge and cell house effluent of a chloralkali plant has been evaluated. (C) 2004 Elsevier B.V. All rights reserved.
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