期刊
INORGANICA CHIMICA ACTA
卷 357, 期 12, 页码 3683-3688出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ica.2004.05.037
关键词
coordination polymer; cavity; channel; photoluminescent property
A novel three-dimensional metal-organic coordination polymer, [Zn-2(HBTC)(2)(H2O)(3)](n) (1) (BTC = 1,2,4-benzenetricarboxylate), has been prepared by aqueous solution reaction of Zn(NO3)(2) . 6H(2)O and BTC at moderate temperature and characterized by IR, TGA and single-crystal X-ray diffraction analysis. The three-dimensional architecture of 1 not only possesses rectangular cavities but also has ordered one-dimensional straight channels. Furthermore, compound 1 shows intense photoluminescent property at room temperature. (C) 2004 Elsevier B.V. All rights reserved.
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