4.8 Article

Topologically driven swelling of a polymer loop

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NATL ACAD SCIENCES
DOI: 10.1073/pnas.0403383101

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Numerical studies of the average size of trivially knotted polymer loops with no excluded volume were undertaken. Topology was identified by Alexander and Vassiliev degree 2 invariants. Probability of a trivial knot, average gyration radius, and probability density distributions as functions of gyration radius were generated for loops of up to N = 3,000 segments. Gyration radii of trivially knotted loops were found to follow a power law similar to that of self-avoiding walks consistent with earlier theoretical predictions.

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