期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2004, 期 19, 页码 4014-4019出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.200400243
关键词
asymmetric catalysis; Michael addition; organocatalyst; peptides
The potential of tripeptides 3, 6 and 12 as chiral catalysts for asymmetric Michael addition reactions in the presence of an achiral additive has been tested in different solvents (CHCl3, acetone, DMF, DMSO and the room-temperature ionic liquid [bmim]PF6). The dependence of yields and enantiomeric excesses on the solvent used has been demonstrated. The experiments show that the combination of additive and peptides provides a catalytic system that appears to be better than the sum of its parts.
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