期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2004, 期 19, 页码 4003-4013出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.200400257
关键词
c-c coupling; cyclotrimerizations; nanostructures; polycycles; semi-empirical calculations
Various C-3-symmetric molecules were prepared by trimerization of acetyl aromatic compounds and subsequently coupled with various boronic acids under Pd-0 catalysis conditions to generate oligoaryl/-heteroaryl C-3-symmetric molecules. Several furan- and thiophene-containing star-shaped molecules were prepared by the use of Suzuki-Miyaura cross-coupling as a key step. Structural and conformational details were explored by semi-empirical molecular orbital theory using the AM1 method.
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