Low electric-field driven ultrahigh electrostrains in Sb-substituted (Na,K)NbO3 lead-free ferroelectric ceramics

Lead-free (Na0.52K0.48)(Nb1-ySby)O-3 (NKNSy) ferroelectric ceramics were reported to exhibit an ultrahigh electrostrain (dynamic d(33)* (=S/E) of 800-1100 pm/V) in a relatively low driving electric field range (1-4 kV/mm). As evidenced by in-situ synchrotron x-ray diffraction and dielectric measurements, the mechanism of generating large strains was ascribed to both the low-field induced reversible rhombohedral-monoclinic phase transition (1-2 kV/mm) and the enhanced domain switching (2-4 kV/mm) owing to the normal to relaxor phase transformation, which contribute to similar to 62% and similar to 38% of the total strain, respectively. The results indicate that the NKNSy compositions would have excellent potentials for applications of lead-free actuator ceramics. (C) 2014 AIP Publishing LLC.