期刊
JOURNAL OF SOLID STATE CHEMISTRY
卷 177, 期 10, 页码 3633-3639出版社
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jssc.2004.06.004
关键词
manganates; rare earth; ferromagnetism; in rare earth manganates; Jahn-Teller distortion; size-disorder; in rare earth manganates
Magnetic and electron transport properties of four series of manganates of the composition La(0.5-x)Ln(x)Sr(0.5)MnO(3) (Ln = Pr, Nd, Gd and Y) have been investigated to examine how the ferromagnetic metallic nature of the parent La compound changes over to antiferromagnetic insulating behavior, with change in Ln and x due to the associated changes in the A-site cation radius as well as the size disorder. When Ln = Pr and Nd, there is a transition from the tetragonal I4/mcm structure to the orthorhombic Immm and Imma structures at x = 0.2 and 0.35, respectively. There is a gradual evolution of the properties from those of La0.5Sr0.5MnO3 to those of Pr0.5Sr0.5MnO3 or Nd0.5Sr0.5MnO3 With increase in x. Thus, when x > 0.2 and > 0.35, respectively, the Pr- and Nd-substituted manganates show ferromagnetic transitions followed by antiferromagnetic transitions at low temperatures, with the ferromagnetic T-C decreasing with increasing x. The Gd and Y series of compounds are all orthorhombic and show a decrease in TC with the increase in x, the ferromagnetism disappearing at high x. At a value of x corresponding to the A-site cation radius of Pr0.5Sr0.5MnO3, the Gd and Y series of compounds exhibit ferromagnetism in the 250-300 K region and undergo an antiferromagnetic transition on cooling. The T-C-T-N gap is sensitive to the disorder arising from the size mismatch. (C) 2004 Elsevier Inc. All rights reserved.
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