期刊
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
卷 42, 期 19, 页码 4847-4861出版社
WILEY
DOI: 10.1002/pola.20212
关键词
microspheres; polyacrylonitrile; template; composite; swelling; single-step swelling
Polyacrylonitrile/polystyrene micrometer-sized composite particles of narrow size distribution were prepared by a single-step swelling of uniform polystyrene template microspheres with emulsion droplets of methylene chloride containing the monomer acrylonitrile and the initiator benzoyl peroxide. Methylene chloride was then evaporated carefully, followed by polymerization of acrylonitrile at 70degreesC within the shrunken template particles. Polymerization of acrylonitrile also occurred at the particles' surface due to the interaction of surface polyacrylonitrile oligoradicals with acrylonitrile dissolved in the aqueous phase. Uniform polyacrylonitrile particles of higher surface area were formed by dissolving the template polystyrene polymer of the composite particles. Surface and bulk characterization of the particles were performed by methods such as FTIR, elemental analysis, TGA-DSC, XRD, XPS, advancing contact angle, light microscope, SEM and cross-sectional TEM. (C) 2004 Wiley Periodicals, Inc.
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