Qualitative and quantitative analysis of organophosphorus pesticide residues using temperature modulated SnO2 gas sensor

Qualitative and quantitative analysis of organophosphorus pesticide residues (acephate and trichlorphon) using temperature modulated SnO2 gas sensor were studied. The testing method employed only a single SnO2-based gas sensor in a rectangular temperature mode to perform the qualitative analysis of pure pesticide vapor and a binary vapor mixture in the air. Experimental results showed that in the range 250-300degreesC and at the modulating frequency of 20 mHz the high selectivity of the sensor could be achieved. The quantitative analysis of the pure pesticide vapor and their mixture were performed by fast Fourier transformation (FFT). The higher harmonics of the FFT characterized the non-linear properties of the response at the sensor surface. The amplitudes of the higher harmonics exhibited characteristic variations that depend on the concentration and the kinetics of pesticide species on the sensor surface. (C) 2004 Elsevier B.V. All rights reserved.