期刊
ORGANIC LETTERS
卷 6, 期 22, 页码 4065-4067出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol048260z
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资金
- NIGMS NIH HHS [GM28965] Funding Source: Medline
Three ring-contracted mimics of shikimate-3-phosphate, formed from the triols by shikimate kinase, were evaluated as substrates of the next enzyme in the pathway, EPSP synthase. The cyclopentylidene analogue (+)-2P was converted enzymatically to the enolpyruvyl derivative, thus demonstrating the second step of an artificial biosynthetic sequence.
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