期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 69, 期 22, 页码 7779-7782出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo048963u
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Ferrocenyl monophosphine ligands have been developed by a method based on palladium-catalyzed Suzuki-Miyaura coupling. The modular procedure creates a rapid synthesis of phosphines with diverse properties. The electron-rich phosphines have been successfully applied to the Suzuki-Miyaura coupling of activated and deactivated aryl chlorides, with low catalyst loading being feasible in the synthesis of tris-ortho-substituted biaryls.
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