期刊
JOURNAL OF THE BRAZILIAN CHEMICAL SOCIETY
卷 15, 期 6, 页码 971-975出版社
SOC BRASILEIRA QUIMICA
DOI: 10.1590/S0103-50532004000600027
关键词
amino alcohols; enamino ketones; oxazines; stereoselective reduction
Reduction of beta-enamino ketones 2 with NaBH4 in glacial acetic acid gave gamma-amino alcohols 1 in 70% to 98% yield with diastereomeric excesses, preferentially the syn product, from 44% to 90%. The stereochemistry of these compounds was confirmed by analysis of their tetrahhydro-1,3-oxazine derivatives 3.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据