期刊
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
卷 42, 期 21, 页码 5482-5487出版社
JOHN WILEY & SONS INC
DOI: 10.1002/pola.20336
关键词
poly(L-lactide); carboxymethyl pullulan; graft copolymer; biodegradable; aggregate
Poly(L-lactide) (PLLA) with terminal primary amino groups (PLLA-NH2) was synthesized and used to construct PLLA-grafted pullulan (Pul-g-PLLA). It consisted of a hydrophilic carboxymethyl Pul (CM-Pul) main chain and hydrophobic PLLA graft chains that were created through a direct coupling reaction between PLLA-NH2 and CM-Pul using 2-ethoxy-1-(ethoxycarbonyl)-1,2-dihydroquinoline as a condensation reagent. Pul-g-PLLAs with over 78 wt % sugar unit content were found to form nanometer-sized aggregates in water. (C) 2004 Wiley Periodicals, Inc.
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