期刊
JOURNAL OF ORGANOMETALLIC CHEMISTRY
卷 689, 期 22, 页码 3582-3592出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2004.07.061
关键词
palladium; Sonogashira reaction; Negishi reaction; binuclear complexes; N-chelate ligands
The binuclear complex [(acac)Pd(oxam)Pd(acac)] 1 (oxam: tetraphenyl oxalic amidinate) has been prepared from H(2)oxam and Pd(acac)(2) in excellent yield. The complex was characterized by elemental analyses, mass spectroscopy, H-1 NMR, C-13 NMR spectroscopy and in the solid state by X-ray single crystal diffraction analyses. 1 consists of a bimetallic centrosymmetric unit in which the planar oxam ligand acts in a bis-chelating fashion. Each palladium center is in a planar environment. The complex 1 acts as highly selective pre-catalyst in the copper-free Sonogashira reaction between 4-bromoacetophenone and phenylacetylene. Its long-time catalytic activity is higher than that of the related binuclear complex 2 (oxam: tetra-p-tolyl oxalic amidinate) or that of the trinuclear compound [(acac)Pd(oxam)Zn(oxam)Pd(acac)] (3), the solid-state structure of which was also determined by an X-ray structural analysis of single crystals. In addition, 2 is an active and extremely selective pre-catalyst for the Negishi reaction between 3,5,6,8-tetrabromophenanthroline and R-CdropC-ZnCl (R: Ph, ((i)prop)(3)Si) to form tetra-alkyne-substituted derivatives. (C) 2004 Elsevier B.V. All rights reserved.
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