期刊
POLYMER DEGRADATION AND STABILITY
卷 86, 期 2, 页码 339-348出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.polymdegradstab.2004.04.020
关键词
unsaturated polyester; phosphorous-containing flame retardant; expandable graphite; MTGA
A series of flame retardant-containing unsaturated polyesters have been developed. The flame retardants include expandable graphite and phosphorous-containing materials (ammonium polyphosphate (APP) and triphenyl phosphate (TPP)). The effects of incorporating different flame retardants into the unsaturated polyesters were investigated by UL-94, DSC, TGA, LOI, MTGA, Py/GC/MS and adiabatic bomb calorimeter. The results indicate that the flame-retarding effect of APP type flame retardant was better than that of the TPP type as the phosphorous-containing flame retardant was the sole additive in this system. Moreover, the flame-retarded effect was further improved as the phosphorous-containing flame retardant and expandable graphite were both added to the polyester. This indicates that a pronounced additive effect was present as the expandable graphite was added to the phosphorous-containing unsaturated polyesters, especially the APP-containing type. (C) 2004 Elsevier Ltd. All rights reserved.
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