期刊
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS
卷 65, 期 11, 页码 1793-1797出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.jpcs.2004.05.006
关键词
MOCVD; nanoparticles; titania; EPR; F center
The concentration of F center in high-surface-area anatase titania nanoparticles prepared by MOCVD are studied with electron paramagnetic resonance measurements at different time and different temperatures. The results show that the kinetics of F center is dominated by surface process rather than bulk process. With increasing temperature, two temperature dependent regions for the concentration of F center can be clearly identified. The starting temperature and activation energy of the surface process are determined to be 357.4 K and 0.085 eV, respectively. The reaction of F center with oxygen is of zero order and the concentration of F center can be well described by [GRAPHICS] (C) 2004 Elsevier Ltd. All rights reserved.
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