期刊
EUROPEAN POLYMER JOURNAL
卷 40, 期 11, 页码 2437-2444出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.eurpolymj.2004.06.013
关键词
montmorillonite; nanocomposites; polystyrene; intra-gallery polymerization; extra-gallery polymerization
Polystyrene/montmorillonite (PS/MMT) nanocomposites were prepared by in situ free radical intercalative polymerization, using 1, 3 and 5 wt% of a new cationic radical initiator-MMT hybrid. The corresponding nanocomposites were designated as PS/MMT-1, PS/MMT-3 and PS/MMT-5, respectively. The silicate layers were well exfoliated and randomly dispersed in the PS/MMT-1 and PS/MMT-3, but were less exfoliated in the PS/MMT-5, due to the predominant extra-gallery polymerization over the intra-gallery polymerization. The unique properties of nanocomposites resulted from the strong interactions between the nano-sized silicate layer surfaces and the polymer chains. The onset temperature of thermal degradation, and the glass transition temperature, increased with increasing hybrid content, up to 3 wt%. The molecular weights of the PS in the PS/MMT-1 and PS/MMT-3 were less than those calculated theoretically, due to the predominant intra-gallery polymerization. (C) 2004 Elsevier Ltd. All rights reserved.
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