Nanoscale domains in strained epitaxial BiFeO3 thin Films on LaSrAlO4 substrate

BiFeO3 thin films with various thicknesses were grown epitaxially on (001) LaSrAlO4 single crystal substrates using pulsed laser deposition. High resolution x-ray diffraction measurements revealed that a tetragonal-like phase with c-lattice constant similar to 4.65 A degrees is stabilized by a large misfit strain. Besides, a rhombohedral-like phase with c-lattice constant similar to 3.99 A degrees was also detected at film thickness of similar to 50 nm and above to relieve large misfit strains. In-plane piezoelectric force microscopy studies showed clear signals and self-assembled nanoscale stripe domain structure for the tetragonal-like regions. These findings suggest a complex picture of nanoscale domain patterns in BiFeO3 thin films subjected to large compressive strains. (C) 2010 American Institute of Physics. [doi:10.1063/1.3456729]