期刊
APPLIED PHYSICS LETTERS
卷 96, 期 3, 页码 -出版社
AMER INST PHYSICS
DOI: 10.1063/1.3284657
关键词
adsorbed layers; carbon nanotubes; nanotube devices; p-n heterojunctions; polymer films; solar cells
资金
- DOE [DE-FG36-06 GO 86072]
- Arkansas Science and Technology Authority (ASTA) [08-CAT-03]
Photovoltaic conversion was achieved from high-density p-n heterojunctions formed between polymer functionalized n-type single wall carbon nanotubes (SWNTs) and underlying p-type Si substrate. Functionalization of SWNTs by amine-rich polymers results in the evolution of tubes from p-type to n-type, and the polyethylene imine (PEI) functionalized SWNT film can serve as both photogeneration sites and a charge carrier collecting/transport layer. Photoremoval of oxygen adsorbed on the nanotubes prior to PEI functionalization can increase the conversion efficiency of the polymer functionalized n-type SWNT photovoltaic devices.
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