期刊
ELECTROCHEMISTRY COMMUNICATIONS
卷 6, 期 11, 页码 1180-1184出版社
ELSEVIER SCIENCE INC
DOI: 10.1016/j.elecom.2004.09.016
关键词
carbon nanotubes; Prussian blue; interaction; electrochemical properties
Chemical functionalization of single-walled carbon nanotubes (SWNTs) has constructed plenty of new structures with ample new properties into them. But the modification was often confined to organic molecules, either by covalence or non-covalence. In this report, SWNTs were successfully functionalized with one kind of electroactive inorganic compounds: Prussian blue (PB). And the molecular interactions between them were firstly investigated. Interestedly, pi-pi stacking interaction coupled with ionic interaction was found between SWNTs and PB. The electrochemical properties of SWNTs-PB were also investigated. It would pave a new pathway to manipulate molecular entities of SWNTs by cooperation with functional inorganic electroactive compounds. (C) 2004 Elsevier B.V. All rights reserved.
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