期刊
APPLIED PHYSICS LETTERS
卷 96, 期 19, 页码 -出版社
AMER INST PHYSICS
DOI: 10.1063/1.3430045
关键词
barium compounds; dielectric polarisation; differential scanning calorimetry; ferroelectric ceramics; lattice energy; multilayers; pyroelectricity; tape casting; thermodynamic properties
资金
- Research Grants Council of the Hong Kong Special Administrative Region, China [PolyU 7195/07E]
- Hong Kong Polytechnic University [A-SA29, G-YX0X]
- National Science Foundation of China [50702005]
The electrocaloric (EC) effect of BaTiO3 multilayer thick film structure was investigated by direct measurement and theoretical calculation. The samples were prepared by the tape-casting method, which had 180 dielectric layers with an average thickness of 1.4 mu m. The thermodynamic calculation based on the polarization-temperature curves predicted a peak heat adsorption of 0.32 J/g at 80 degrees C under 176 kV/cm electric field. The direct measurement via differential scanning calorimeter showed a much higher EC effect of 0.91 J/g at 80 degrees C under same electric field. The difference could result from the different trends of changes of electric polarization and lattice elastic energy under ultrahigh electric field. (C) 2010 American Institute of Physics. [doi:10.1063/1.3430045]
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