Retention, kinetics and thermodynamics profile of cadmium adsorption from iodide medium onto polyurethane foam and its separation from zinc bulk

The sorption behaviour of 2.5 x 10(-5) M solution of Cd(II) on polyurethane foam (PUF) from iodide medium have been investigated. The conditions were optimized from aqueous solutions of different pH (1-10) and of acids of varied concentration (0.01-1.0 M). The maximum concentration of KI was found to be 0.24 M and equilibration time was established to be 20 min. The data successfully followed the Freundlich and Dubinin-Radushkevich (D-R) isotherms at low metal ion concentration while Langmuir isotherm followed at higher metal ion concentration. The Freundlich parameter 1/n = 0.66 +/- 0.02 have been evaluated whereas D-R isotherm yields the sorption free energy E = 10.5 +/- 0.1 kJ mol(-1) indicating ion exchange type chemisorption. The monolayer coverage (X-L) constant of Langmuir isotherm was found to be 23.7 +/- 0.4 mg g(-1). The numerical values of thermodynamics parameters enthalpy (DeltaH), entropy (DeltaS) and Gibbs free energy (DeltaG) indicated the endothermic and spontaneous nature of sorption. The Scatchard plot analysis was tested to evaluate the binding sites of the PUF and stability constants of sorption were determined. On the basis of these parameters, the sorption mechanism was discussed. Among the foreign ions tested, Pb(II), Hg(II), cyanide and nitrite should be absent. The clean separation of Cd(II) from Zn(II) ions in the ratio 1:250, respectively, was achieved by column chromatography. (C) 2004 Elsevier B.V. All rights reserved.