期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 126, 期 45, 页码 14899-14909出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja047939v
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Dynamic electrochemical studies, incorporating catalytic voltammetry and detailed potential-step manipulations, provide compelling evidence that the oxidized inactive state of [NiFe]-hydrogenases termed Unready (or Ni-A) contains a product of partial reduction of O(2) that is trapped in the active site.
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